联合动力有限公司

二十年聚合物锂离子电池商业化 Plastic Lithium Ion Battery (PLIB) Business: 1994 Bellcore Patented the Plastic Lithium Ion (PLI) Technology or Solid State Battery, and First All-Plastic Battery of Johns Hopkins as One of 100 Top Scientific Developments and Inventions for 1996

二十年聚合物锂离子电池商业化 Plastic Lithium Ion Battery (PLIB) Business: 1994 Bellcore Patented the Plastic Lithium Ion (PLI) Technology or Solid State Battery, and First All-Plastic Battery of Johns Hopkins as One of 100 Top Scientific Developments and Inventions for 1996

二十年聚合物锂离子电池 (PLIB):

 ·石墨插层混合物 (GIC): 1981年, 贝尔实验室 (Bell Laboratories)研制了石墨阳极代替锂金属电池的金属锂阳极从而使锂离子电池变成现实, 1982年获嵌锂石墨电极专利;
 ·锂离子电池(LIB)从1992年由日本索尼SONY公司商业化开始;
 ·1993年, 美国 Bellcore(贝尔电讯公司)首先报导了采用偏氟乙烯一六氟丙烯(PVDF-HFP) 工艺制造成聚合物锂离子电池(PLIB)或固态电池 (SSB), 1996年, 以PVDF—HFP共聚物为材料的多孔膜技术(物理交联法)及多孔凝胶聚合物电解质商品化获发明专利 (US Patent 5,540,741);
 ·1996年, 第一个全塑料电池由美国约翰霍普金斯大学 (Johns Hopkins University) 研制成功, 被评为1996年度100项科学重大发明之一;
 ·1997年, 均匀凝胶聚合物电解质材料技术(化学交联法)获发明专利(US Patent 5,603,982);
 ·1997年, 聚合物锂离子电池开始商业化;
 ·2000年以来, 聚合物锂离子电池开始3C便携式及电信电源, 轻型电动车动力电池, 电力储能 电池市场;
 ·具更高能量的聚合物锂离子电池(PLIB)将成为安全目标的电动汽车用锂离子电池之一。

20-Year R&D of Polymer Lithium-ion Battery:

 ·Early intercalation concept and graphite intercalation compounds (GICs): In 1981, safer lithium-ion batteries (LIB) came into reality when Bell Laboratories developed a workable graphite anode to provide an alternative to the metallic lithium anode of unsafe lithium metal battery (LMB). In 1982, Bell Laboratories were awarded a US patent on the use of lithiated graphite (LiC6) in liquid electrolyte;
 ·In 1992 Sony started the business of lithium-ion battery (LIB);
 ·1994 Bellcore (Bell Communications Research) patented the Plastic Lithium Ion (PLI) technology or solid state battery: Bellcore (Telcordia Technologies) researchers pioneered the plastic Li-ion battery PLiON technology and developed a patented fabrication process utilizing an electrochemically inert fluoropolymer matrix that entraps liquid electrolyte. The battery looks and feels dry, while it performs just like the cells that contain liquid electrolyte;
 ·The first all-plastic battery of Johns Hopkins University as one of 100 top scientific developments and inventions for 1996;
 ·In 1997 the commercialization of polymer lithium-ion battery (PLIB): The revolutionary polymer-based plastic lithium-ion rechargeable battery technology known as the PLiON battery technology, which was licensed to 22 companies worldwide. Products based on this technology are now entering the cell phone and laptop computer market. Many LIB manufacturers such as SONY and SANY used modified assembly lines to simplify PLIB production processes.
 ·The business of polymer lithium-ion battery in the markets of 3C, LEV power battery, telecommunications and grid energy storage: The plastic Lithium-ion battery is a promising power source for many rapidly growing applications across industries ranging from telecommunications and consumer electronics to electric vehicles and transportation.
 ·High energy density polymer lithium-ion battery would become one of the safer PHEV or EV batteries.

Bellcore’s thin-layered bicell battery 聚合物锂离子电池单片电芯 (Bi-Cell)组装工艺: The laminate plastic-lithium ion (PLI) bicell materials developed by Bellcore (Telcordia Technologies) with one pseudo-bipolar plate (anode here), and each side of the bicell discharges at a normal voltage of 3.7 V and the total bicell specific energy is ~165 Wh/kg at a 1C discharge rate. The bicells can be heat-pressed and the laminate can be heal-sealed to form a pouch package for thin-layered bicell batteries.

聚合物锂离子电池4种主要组装生产工艺流水线: The general production processes of Bellcore polymer lithium-ion battery assembly line using stacking, sometime the complex production processes, which led to form 4 main kinds of production assembly lines based on unicell or bicell configuration as well as stacking or winding.


http://www.argreenhouse.com/ESR/plfab.htm

SONY 凝胶卷绕工艺与SANY 卷绕凝胶工艺.

http://www.sony.net/Products/SC-HP/cx_news/vol18/pdf/cxeye.pdf
http://www.celltech.dk/pdffiles/Sany_Polymer2009_E.pdf

"All Plastic Battery Unveiled." Success Stories. [Rome Laboratories, April 1997]
http://www.jhu.edu/news_info/news/home96/nov96/batt.html
http://ksykang.tripod.com/chem/CHEM_PLA.HTM
http://www.sciamdigital.com/index.cfm?fa=Products.ViewIssuePreview&ISSUEID_CHAR=F1E36413-4C42-4E84-BCE9-A10BEB1E9D3&ARTICLEID_CHAR=D4A6B02D-A7CB-4403-A624-81B69B9291A

http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=7938846
http://www.psu.edu/ur/2002/colorlecs.html http://www.electrochem.org/dl/interface/fal/fal03/IF8-03-pages9-12.pdf http://www.marketingtechie.com/search-post.asp
http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8021525
http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8021508

20-Year R&D History:

 ·1993, Ionomer-coated and dispersed inorganic nanoparticles formulation and coating;
 ·1994, Enhanced thermoplastic single-ion conductor and solid-state Li-ion polymer battery (PLIB);
 ·1995, Modified aramid fiber fabric separator for nickel-hydrogen battery;
 ·1996, Insulating polymer coatings for high-temperature self-solderable enameled round winding wires (QA/UEW, class 180);
 ·1997, Tri-layer all-plastic Li-ion battery (PLIB);
 ·1998, Polymer-metal electrode interface engineering;
 ·1999, Enhanced plastic adhesion and laminate packaging;
 ·1999, Electronic-ionic hybrid conductor;
 ·2000, Fast-response solid-state Li-ion electrochemical cell;
 ·2001, Thin-film cell assembly, filling and sealing;
 ·2001, In-situ polymerization technology of gel polymer;
 ·2002, High energy density plastic thin-film capacitor with graceful failure;
 ·2001, 2D huge p-conjugated delocalized charge macromolecules (superelectronic polarized polymer and graphene) as high density charge and energy storage materials;
 ·2002, High-k polymer nanocomposite dielectric capacitor energy storage;
 ·2003, High energy density plastic transducer with graceful failure;
 ·2004, Low-voltage driven polymer nanocomposite membrane transducer;
 ·2005, Pre-charging method and pre-charged thin-film built-in bias integration;
 ·2006, Pre-charged transistor circuitry and integrated analog front end (iAFE);
 ·2007, Electret and piezo-polymer thin films and piezo-cables;
 ·2007, Piezo-polymer film cellular foam transducer;
 ·2008, Electro-spinning nanofiber nonwoven fabrics;
 ·2008, Hybrid nanofiber microporous membrane;
 ·2007, Engineering solutions for scalable battery energy storage;
 ·2007, Fiber surface modification and coating and fiber prepregs for pre-impregnated, fiber-reinforced laminate composites;
 ·2008, Robustly nano-tailored structure for high-throughput high-temperature piezoelectric films;
 ·2009, Piezo-polymer cell;
 ·2008, TFC membrane electrode and current collector prepregs;
 ·2008, TFC membrane electrolyte and separator;
 ·2009, Gelled electrolyte enhancement;
 ·2009, TFC membrane coating, laminate packaging and cell stacking;
 ·2008, Pre-charged electrode;
 ·2010, High-capacity cathode;
 ·2010, High-temperature (1800C) TFC plastic electrolyte high-power-density cell packaging;
 ·2008, Thin-layered bi-cell configuration;
 ·2010, Current collector pre-treatment and electrode slurry formulation and mixing;
 ·2008, TFC electrode membrane and slitting;
 ·2009, Bi-cell packaging and stacking;
 ·2011, Battery cell formation, degassing, aging, capacity grading and sorting;
 ·2010, Li-polymer cell design and packaging;
 ·2012, PLIB pouch cell production assembly line;

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